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Lessons offered by Rolando
  • Individual
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  • at his home
  • at your home
Taught subjects
  • Mathematics
  • Algebra
  • Physics
  • Chemistry
  • Physics - Chemistry
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  • MBA

PhD Solid State Physics and Physical Chemistry of Materials for Abatement

Methodology

I'm a highly educated Physics Preofesor who could as well teach Mathematics. Have thirty five years of expeiricence teaching General, Modern, Materials Physics, Physical Adsorption, Catalysis, Instrumental for Physicists, Chemist and Engieneers. Have expeience in Powder X-ray diffraction-crystallography; scanning-transmission-electron-optical-microscopy-&-Energy dispersive X-ray-analysis; Mössbauer spectrometry; Raman and IR spectrometry; Impedance spectrometry; thermo-differential, thermo-reduction, thermo-desorption and thermo-gravimetric-analysis; mass-spectrometry; X-ray-photoelectron spectrometry; X-ray-fluorescence;, additionally, invented-constructed-&-tested two new methods; specifically, thermo-dielectric-analysis and Fourier-transform-infrared-thermo-programmed-desorption, together with a new dew point sensor and a magnetic balance; finally, have a large experience applying the software: MS-Office, Origin, Peakfit, Pascal, Basic, Windows, Powder-Cell, Rietveld and Le-Vail.
ii. Natural-&-synthetic zeolites: my role to made Cuba (my country-land) the world leader in Natural Zeolite Science and Technology was “sine-qua-non”, this fact made me one of the worldwide key researchers in this field, as was acknowledged by Dr. Frederick Mumpton, President of the International Committee on Natural Zeolites; besides, developed from laboratory to pilot plant a process for the synthesis of Na-Y zeolite, by the hydrothermal transformation of a natural clinoptilolite and a Na-A zeolite using the liquors remaining after the hydrothermal transformation; furthermore synthesized AlPO-5, CoAPO-5, MnAPO-5, ZnAPO-5 and FeAPO-5 molecular sieves; finally, researched solid state reactions milling mixtures of Na-Y and Na-A zeolites along with AlPO4.3H2O and a natural erionite zeolite plus Fe2(SO4)3.5H2O.
iii. Adsorption-&-Diffusion: my undertaking in these fields, as described in my books along with thirty-seven peer reviewed articles (adsorption) and eight (diffusion) have been outstanding; since, together with exceptional contributions to the theory made extensive experimental research, alone with the construction of pilot plants for air drying and “in-situ” natural gas cleaning reactors, together with filters for ammonia removal and profound gas drying, using natural zeolite packed bed adsorption reactors and experimental facilities to study single-component diffusion and two-component co-diffusion and counter-diffusion of hydrocarbons in zeolites at different temperatures using the FTIR methodology.
iv. Catalysis: have a large experience of successful research during which, produced Pt catalysts for methanol fuel cells; developed a phenol decomposition process using the mechanical activation of a rutile catalyst; deduced mathematical expressions for the calculation of the adsorption-enthalpy of hydrocarbons analyzing their relation to the activation energy of the cracking reaction; besides, studied pyrrole-furfural-&-aniline oligomerization; plus, citronellal cyclization, hexane hydrogenation and ethanol dehydration on zeolites; together with the research of the “catalytic effect” of natural zeolites in fermentation processes; besides, designed-&-constructed flow catalytic reactors for ethanol-dehydration, hexane-reduction and waste-water-cleaning and batch reactors for mechanical activation and oligomerization processes.
v. Magnetism: made relevant studies using the vibrating sample magnetometer method, to establish that, akaganeite displayed a superparamagnetic behavior; Cu(II) hexacyanoferrate (III) polymorph exhibited an antiferromagnetic conduct; layered porous molecular magnet shows an appreciable effective magnetic moment; Ni-&-Cu and Zn-&-Cd nitroprussides showed paramagnetic and diamagnetic behaviors respectively; and SWCNT-Fe3O4 composites exhibited the presence of a large quantity of catalytically active Lewis acid sites; hence, since all these materials are porous their magnetic properties could be modified during adsorption, then can be used as gas sensors.
vi. Ion conduction: have accomplishments in different research projects such as the conception of a new mechanism for proton conduction in perovskites; role of the framework structure of BaCe0.95Y0.05O3-ÎŽ, under hydrogen diffusion, in the proton conduction rate; together with the elucidation of the mechanism of direct current transport in zeolites.
vii. Ion exchange: investigated the removal of Pb2+, Cu2+, Co2+ and Ni2+ from water solutions by dynamic ionic exchange in a zeolite packed ion exchange flow reactor; moreover, studied the location and reducibility of Ni ions in HEU type zeolite in order to learn how to produce a nickel zeolite catalyst for the hydrogenation of hexene and benzene; additionally, used ion exchange in natural zeolites in aquaculture, showing that the fishes in a pond where zeolite was poured, survived more time than in normal conditions without zeolite; finally, made a key contribution to the theory of ion-exchange by establishing the trend of the exchange reaction by means of the measurement of the heat evolved during ion-exchange, together with the deduction of the mathematical expression to calculate this parameter.
viii. Design and construction of new research methods: Thermo-Dielectric-Analysis (TDIA)-&- Dielectric Spectrometry (DS); for both methods, the sensor circuit was an operational amplifier plugged in for impedance comparison with two capacitors, i.e., sample and reference capacitors; for TDIA, both the sample-filled and alumina-filled cylindrical capacitors were enclosed in the equipment furnace, fed with the input voltage, VI, generated with a rectified sinusoidal signal, Vin, of 400 Hz and 25 V, then the output voltage, VO, was fed to an X-Y-plotter to get the VO-T thermos-dielectric profile; for DS, the sample capacitor was cylindrical, it was enclosed in a Pyrex tube that comprised two welded wolfram wires connecting the sample capacitor plates with the sensor circuit; similarly as reference was used a carefully calibrated commercial capacitor; moreover, the sample capacitor was enclosed in a furnace and the enclosing Pyrex tube was hooked up to a vacuum system comprising an adsorption-volumetric facility to measure isotherms; finally, the circuit was fed with a wave generator (VI) while an oscilloscope measured the output signal (VO) to get the dielectric spectra; lastly, the Fourier-transform-infrared-thermo-programmed-desorption methodology consisted of a commercial high temperature IR cell, that allowed gas flow-&-heating; then, the adsorbent sample was pressed to produce a self-supported thin wafer, that was placed in the IR cell, then heated while pure nitrogen was flowed to degas it; thereafter, to adsorb benzene, toluene or ethylbenzene, the pure nitrogen gas was saturated with these hydrocarbons by flowing it in liquid benzene, toluene or ethylbenzene; next, the sample wafer was contacted with the gas flow while the FTIR spectrometer in kinetic mode acquired spectra of 1 scan per spectrum, 0.85 seconds per scan, without delay between scans, acquiring enough spectra to draw an absorbance versus temperature profile.

Background

Material Characterization, Porous Materials, Powder X-ray Diffraction, Synthesis, Thermal Analysis, Materials Physics, Solid-State Chemistry, 3D Crystallography, Adsorption and Adsorbents, Statistical Physics, Nonequilibrium Statistical Physics, Applied Thermodynamics, Surface Science, Mass Spectrometry, Calorimetry, Broadband Dielectric Spectroscopy, Impedance Spectroscopy, Thermodielectric analysis, FTIR programmed desorptioin, Infrared Spectroscopy , Thermogravimetric Analysis, Differential Scanning Calorimetry, Zeolites, Nanomaterials, SEM Analysis, DSC, Nanomaterials Synthesis, FTIR Analysis, Catalyst, Reaction Mechanisms, Experimental Physics, Rietveld Method, Evaporation, Perovskites, Phase Transformations, Raman Spectroscopy, Differential Thermal Analysis, Thin Films and Nanotechnology, Solid State Physics, Catalysis, EDAX, Adsorption, Materials Science, Materials, Ceramics, TPD, Mesoporous Materials, Conducting Polymers, Polyaniline, Electrical Conductivity, Composite Material, X-ray Diffraction, Sonochemistry, Electrochemistry, Higher Education, TGA, Material Characteristics, Scanning Electron Microscopy, Carbon Nanotubes, Chemical Vapor Deposition, Crystal, DFT Calculations, XRD Analysis, Advanced Materials, Heat Treatment, Wastewater, Nanopores, Porosity, Nanoparticle Synthesis, Nanostructured Materials, DRX, Surface Properties, Heterogeneous Catalysis, Catalyst Characterization, Thin Film DepositionAs result, of this immense activity, published: 135 papers, 5 books, 16 chapters, 16 patents, 43 extended abstracts and have presented 183 oral and poster papers at scientific conferences. Additionally, delivered courses on General-Modern-Statistical-Quantum-&-Solid State Physics, General-&-Physical Chemistry, Materials Characterization Methods, Calculus and Mathematical Methods for Physicists. Have finished a BSc in Physics at Havana University (Magna Cum Laude, 1970), a MSc in Surface Physics in the National Center for Scientific Research, Cuba–Dresden University of Technology, Germany (Summa Cum Laude, 1972), and a PhD in Solid State Physics at the National University for Science and Technology (Summa Cum Laude, 1978). Moreover, completed postdoctoral stints at the Dresden University of Technology (1978); Moscow State University (1982), Institutes of Physical Chemistry and Chemical Physics, Russian Academy of Sciences (1983), and Central Institute for Chemistry Hungarian Academy of Science (1984), with first class scientists.

Rates

Rate for a 1-hour lesson. : $200/h

Details

My rate is $ 200 per hour

Lessons offered by Rolando
Individual
In group
The lessons will be held
at his home
at your home
Taught subjects
  • Mathematics
  • Algebra
  • Physics
  • Chemistry
  • Physics - Chemistry
Levels
  • Elementary School
  • Middle School
  • Sophomore
  • Junior
  • Senior
  • Advanced Technical Certificate
  • College
  • Adult Education
  • MBA

Rolando's resume

Materials for Art and Science Use
Research
PO Box 2017, PMB 405
Las Piedras, PR 00771
Mexico (concealed information)
Phone: (concealed information)
Mobile: [mobile]
Fax: [fax]
Website: (concealed information)







Rolando M. A. Roque-Malherbe, PhD
Education
Sep 1974 – Jan 1978 National University of Science and Technology
PhD, Solid State Physics
Moscow, Russia
Jul 1970 – Mar 1972 National Center for Scientific Research
Master of Science, Chemical Physics
Havana, La Habana, Cuba
Aug 1965 – Jun 1970 University of Havana
Bachelor of Science, Physics
, Cuba
Research and Education Experience
Apr 2015 – present President
Materials for Art and Science Use, Research and Development
Las Piedras, Las Piedras, Puerto Rico
Collaborating, by request, with private customers and the Chemistry Department of the UPR in: elucidation of the crystallographic structure, study the thermodynamics of adsorption and the adsorption induced framework expansion effect of porous materials.
Jul 1999 – Apr 2015 Dean-Director-Professor
Universidad del Turabo, Institute of Physical-Chemical Applied Research (IPCAR)
Gurabo, Puerto Rico, Dean of Science, PI of NASA, AMGEN and MIE-NSF; thereafter, Director of IPCAR, PI of NSF and DoE projects. Supervised: 25 graduate, 74 undergraduate students,
Apr 1998 – May 1999 Lectturer
Barry University, Mathematics and Computer Science
Miami, Florida, United States
Mathematics tutor in the Learning Center
May 1997 – Feb 1998 Research Professor
Clark Atlanta University, Center for Theoretical Studies of Physical Systems
Atlanta, Georgia, United States
I wrote the first chapter of my book Adsorption and Diffusion in Nanoporous Materials were was produced, as was recognized in the Journal Chromatographia 66, (7/8) (2007) “a very well thought out introduction to statistical mechanics”
Dec 1993 – Aug 1996 Senior Researcher
Chemical Technology Institute, Adsorption and Diffusion
Valencia, Valencia, Spain
Made a comprehensive study of hydrocarbon diffusion in microporous materials; in addition, created models for the calculation of the self diffusion coefficient, along with isotherms describing adsorption in microporous materials
Jan 1984 – Feb 1985 Post Doc in the Institute of Chemical Physics Supervised by Dr E D Makarov in the Goldanski's Mosbauer Spectrometry Deprtment
Russian Academy of Sciences, Mossbauer Spectrometry, Institute of Chemical Physics
Moscow, Russia
Intensive training in Mossbauer Spectrometry in the Correspondent Member Dr. Vitalli I. Goldanskii group, under the supervision of Dr. Evgeny F. Makarov
Sep 1982 – Aug 1983 Post Doc In the Department of Adsortion Process Lead By the Academic M M Dubinin
Institute of Physical Chemistry Russian Academy of Sciences,
,
Feb 1971 – Sep 1992 Head of Department, Laboratory Director and Senior Researche
Centro Nacional de Investigaciones Cientificas, Zeolites Laboratory, Department of Applied Mathematics and Material Science Laboratory
, Cuba
My role to made Cuba the world leader in Natural Zeolite Science and Technology was “sine-qua-non”, this fact made me one of the worldwide key researchers in this field, as was acknowledged by the International Committee on Natural Zeolites.
Some Awards & Grants
Apr 2015 Grant: Adsorption in nanoporous materials. Theory of High Pressure Adsorption. Framework Deformations
Mar 2014 Award: Five awards for big amount of federal fund
Dec 2013 Grant: Physical Adsorption Laboratory
Dec 2012 Grant: XRD Laboratory
Jun 1988 Award: Medal for Cuban Education
Feb 1986 Award: Three times best researcher in Cuban Science
Feb 1986 Award: Five time been between the best researchers in Cuban Higher Education
Skills & Activities
Skills Material Characterization, Porous Materials, Powder X-ray Diffraction, Synthesis, Thermal Analysis, Materials Physics, Solid-State Chemistry, 3D Crystallography, Adsorption and Adsorbents, Statistical Physics, Nonequilibrium Statistical Physics, Applied Thermodynamics, Surface Science, Mass Spectrometry, Calorimetry, Broadband Dielectric Spectroscopy, Impedance Spectroscopy, Thermodielectric analysis, FTIR programmed desorptioin, Infrared Spectroscopy , Thermogravimetric Analysis, Differential Scanning Calorimetry, Zeolites, Nanomaterials, SEM Analysis, DSC, Nanomaterials Synthesis, FTIR Analysis, Catalyst, Reaction Mechanisms, Experimental Physics, Rietveld Method, Evaporation, Perovskites, Phase Transformations, Raman Spectroscopy, Differential Thermal Analysis, Thin Films and Nanotechnology, Solid State Physics, Catalysis, EDAX, Adsorption, Materials Science, Materials, Ceramics, TPD, Mesoporous Materials, Conducting Polymers, Polyaniline, Electrical Conductivity, Composite Material, X-ray Diffraction, Sonochemistry, Electrochemistry, Higher Education, TGA, Material Characteristics, Scanning Electron Microscopy, Carbon Nanotubes, Chemical Vapor Deposition, Crystal, DFT Calculations, XRD Analysis, Advanced Materials, Heat Treatment, Wastewater, Nanopores, Porosity, Nanoparticle Synthesis, Nanostructured Materials, DRX, Surface Properties, Heterogeneous Catalysis, Catalyst Characterization, Thin Film Deposition
Languages English, Russian, Spanish
Scientific Memberships International Committee on Natural Zeolites
International Zeolites Association
Interests Opera Singing, Classical Music, Philosophy and Politics

Citizenship: American.
Summary: Have worked in the National Center for Scientific Research, Cuba (1978-1992) where, as laboratory director, researcher and doctoral supervisor, hardly labored to made my research group the world leader in Natural Zeolites Science-&-Technology, as was accepted by the International Committee on Natural Zeolites; here, obtained, the equivalent of circa five million dollars in research funds. In 1993, after been the most awarded Cuban scientist ever, due to a politic confrontation with the Cuban regime, left my country-land with my family as a political refugee owing to a negotiation lead by my friend-&-colleague Dr. Javier Solana-Madariaga, former Foreign Affairs Minister of Spain and the European Union. Next, worked at the Institute of Chemical Technology (1993-1996), Valencia, Spain; one of the elite research centers in, catalysis, energy storage, molecular dynamics and physical adsorption; later, performed my research at Clark Atlanta University, Atlanta, Georgia (1997-1998); subsequently was Lecturer at Barry University, Miami, Florida, USA (1998-1999). Thereafter, was dean-institute director-&-full professor of the School of Science at University of Turabo, Gurabo, PR (1999-2015), where was the most awarded scientist yet, obtaining more than three million dollars in external funds to run projects in: materials for energy storage, heterogeneous-photo-&-electro-catalysis, pollution abatement, nanomaterials impedance analysis and environmental electrochemistry. In April 2015 funded my Company named Materials for Art and Science Use, where under contract perform Materials Characterization Services to the University of Puerto Rico, Syrviatek, Carolina, PR and Solid Current Energy, Ontario, Canada. As result, of this immense activity, published: 135 papers, 5 books, 16 chapters, 16 patents, 43 extended abstracts and have presented 183 oral and poster papers at scientific conferences. Additionally, delivered courses on General-Modern-Statistical-Quantum-&-Solid State Physics, General-&-Physical Chemistry, Materials Characterization Methods, Calculus and Mathematical Methods for Physicists. Have finished a BSc in Physics at Havana University (Magna Cum Laude, 1970), a MSc in Surface Physics in the National Center for Scientific Research, Cuba–Dresden University of Technology, Germany (Summa Cum Laude, 1972), and a PhD in Solid State Physics at the National University for Science and Technology (Summa Cum Laude, 1978). Moreover, completed postdoctoral stints at the Dresden University of Technology (1978); Moscow State University (1982), Institutes of Physical Chemistry and Chemical Physics, Russian Academy of Sciences (1983), and Central Institute for Chemistry Hungarian Academy of Science (1984), with first class scientists. Additionally, the journal “Materials Today” in a note published in March 20, 2010, recognized that I was one of the creators, or the creator, of a new field in Materials Science, namely: energy and pollution abatement uses of materials, as described in my book “The Physical Chemistry of Materials, CRC Press, 2009. Similarly, the journal “Chromatographia 66, (7/8) (2007)” acknowledged my contribution to Statistical Physics as explained in my book “Adsorption and Diffusion in Nanoporous Materials”, CRC Press, 2007. I’m currently American citizen.
Core Competencies
i. Skills: Powder X-ray diffraction-crystallography; scanning-transmission-electron-optical-microscopy-&-Energy dispersive X-ray-analysis; Mössbauer spectrometry; Raman and IR spectrometry; Impedance spectrometry; thermo-differential, thermo-reduction, thermo-desorption and thermo-gravimetric-analysis; mass-spectrometry; X-ray-photoelectron spectrometry; X-ray-fluorescence;, additionally, invented-constructed-&-tested two new methods; specifically, thermo-dielectric-analysis and Fourier-transform-infrared-thermo-programmed-desorption, together with a new dew point sensor and a magnetic balance; finally, have a large experience applying the software: MS-Office, Origin, Peakfit, Pascal, Basic, Windows, Powder-Cell, Rietveld and Le-Vail.
ii. Natural-&-synthetic zeolites: my role to made Cuba (my country-land) the world leader in Natural Zeolite Science and Technology was “sine-qua-non”, this fact made me one of the worldwide key researchers in this field, as was acknowledged by Dr. Frederick Mumpton, President of the International Committee on Natural Zeolites; besides, developed from laboratory to pilot plant a process for the synthesis of Na-Y zeolite, by the hydrothermal transformation of a natural clinoptilolite and a Na-A zeolite using the liquors remaining after the hydrothermal transformation; furthermore synthesized AlPO-5, CoAPO-5, MnAPO-5, ZnAPO-5 and FeAPO-5 molecular sieves; finally, researched solid state reactions milling mixtures of Na-Y and Na-A zeolites along with AlPO4.3H2O and a natural erionite zeolite plus Fe2(SO4)3.5H2O.
iii. Adsorption-&-Diffusion: my undertaking in these fields, as described in my books along with thirty-seven peer reviewed articles (adsorption) and eight (diffusion) have been outstanding; since, together with exceptional contributions to the theory made extensive experimental research, alone with the construction of pilot plants for air drying and “in-situ” natural gas cleaning reactors, together with filters for ammonia removal and profound gas drying, using natural zeolite packed bed adsorption reactors and experimental facilities to study single-component diffusion and two-component co-diffusion and counter-diffusion of hydrocarbons in zeolites at different temperatures using the FTIR methodology.
iv. Catalysis: have a large experience of successful research during which, produced Pt catalysts for methanol fuel cells; developed a phenol decomposition process using the mechanical activation of a rutile catalyst; deduced mathematical expressions for the calculation of the adsorption-enthalpy of hydrocarbons analyzing their relation to the activation energy of the cracking reaction; besides, studied pyrrole-furfural-&-aniline oligomerization; plus, citronellal cyclization, hexane hydrogenation and ethanol dehydration on zeolites; together with the research of the “catalytic effect” of natural zeolites in fermentation processes; besides, designed-&-constructed flow catalytic reactors for ethanol-dehydration, hexane-reduction and waste-water-cleaning and batch reactors for mechanical activation and oligomerization processes.
v. Magnetism: made relevant studies using the vibrating sample magnetometer method, to establish that, akaganeite displayed a superparamagnetic behavior; Cu(II) hexacyanoferrate (III) polymorph exhibited an antiferromagnetic conduct; layered porous molecular magnet shows an appreciable effective magnetic moment; Ni-&-Cu and Zn-&-Cd nitroprussides showed paramagnetic and diamagnetic behaviors respectively; and SWCNT-Fe3O4 composites exhibited the presence of a large quantity of catalytically active Lewis acid sites; hence, since all these materials are porous their magnetic properties could be modified during adsorption, then can be used as gas sensors.
vi. Ion conduction: have accomplishments in different research projects such as the conception of a new mechanism for proton conduction in perovskites; role of the framework structure of BaCe0.95Y0.05O3-ÎŽ, under hydrogen diffusion, in the proton conduction rate; together with the elucidation of the mechanism of direct current transport in zeolites.
vii. Ion exchange: investigated the removal of Pb2+, Cu2+, Co2+ and Ni2+ from water solutions by dynamic ionic exchange in a zeolite packed ion exchange flow reactor; moreover, studied the location and reducibility of Ni ions in HEU type zeolite in order to learn how to produce a nickel zeolite catalyst for the hydrogenation of hexene and benzene; additionally, used ion exchange in natural zeolites in aquaculture, showing that the fishes in a pond where zeolite was poured, survived more time than in normal conditions without zeolite; finally, made a key contribution to the theory of ion-exchange by establishing the trend of the exchange reaction by means of the measurement of the heat evolved during ion-exchange, together with the deduction of the mathematical expression to calculate this parameter.
viii. Design and construction of new research methods: Thermo-Dielectric-Analysis (TDIA)-&- Dielectric Spectrometry (DS); for both methods, the sensor circuit was an operational amplifier plugged in for impedance comparison with two capacitors, i.e., sample and reference capacitors; for TDIA, both the sample-filled and alumina-filled cylindrical capacitors were enclosed in the equipment furnace, fed with the input voltage, VI, generated with a rectified sinusoidal signal, Vin, of 400 Hz and 25 V, then the output voltage, VO, was fed to an X-Y-plotter to get the VO-T thermos-dielectric profile; for DS, the sample capacitor was cylindrical, it was enclosed in a Pyrex tube that comprised two welded wolfram wires connecting the sample capacitor plates with the sensor circuit; similarly as reference was used a carefully calibrated commercial capacitor; moreover, the sample capacitor was enclosed in a furnace and the enclosing Pyrex tube was hooked up to a vacuum system comprising an adsorption-volumetric facility to measure isotherms; finally, the circuit was fed with a wave generator (VI) while an oscilloscope measured the output signal (VO) to get the dielectric spectra; lastly, the Fourier-transform-infrared-thermo-programmed-desorption methodology consisted of a commercial high temperature IR cell, that allowed gas flow-&-heating; then, the adsorbent sample was pressed to produce a self-supported thin wafer, that was placed in the IR cell, then heated while pure nitrogen was flowed to degas it; thereafter, to adsorb benzene, toluene or ethylbenzene, the pure nitrogen gas was saturated with these hydrocarbons by flowing it in liquid benzene, toluene or ethylbenzene; next, the sample wafer was contacted with the gas flow while the FTIR spectrometer in kinetic mode acquired spectra of 1 scan per spectrum, 0.85 seconds per scan, without delay between scans, acquiring enough spectra to draw an absorbance versus temperature profile.
Publications
Books
Rolando M. A. Roque-Malherbe: Adsorption and Diffusion in Nanoporous Marterials (2nd edition). 12/2017; CRC Press.
Rolando M. A. Roque-Malherbe: Adsorption and DIffusion in Nanoporous Materials (Chinese Translation) 2017. Edited by Barbara Glunn, 01/2017; CRC Press.
Rolando M. A. Roque-Malherbe: Electrochemistry. Energy and Environmental Applications, Lambert Publishers, Germany, 2017.
R. Roque-Malherbe: The Physical Chemistry of Materials: Applications in Pollution Abatement and Sustainable Energy.. Edited by Lance Wobus, 10/2009; CRC Prance.
R. M. A. Roque-Malherbe: Adsorption and Diffusion in Nanoporous Materials. Edited by Lance Wobus, 01/2007; CRC Press., DOI:10.1201/(concealed information)
R. Roque-Malherbe: Physical Chemistry of Zeolites. 01/1988; Publishing Department of the Ministry of Higher Education, Havana, Cuba.
R. Roque-Malherbe: Physical Adsorption of Gases. 01/1987; Publishing Department of the Ministry of Higher Education. Havana, Cuba.
Book Chapters
R. M. A. Roque-Malherbe: Porous Polymers. Porous Polymers, Edited by Editors: M. S. Silverstein, N. Cameron and M. Hillmyer, 01/2011: chapter Surface Area and Porosity Characterization of Porous Polymers, in Porous Polymers; J. Wiley & Sons., DOI:10.1002/978(concealed information).ch5
R. Roque-Malherbe: Membrane Fouling: Recent Strategies and Methodologies for its Minimization. Handbook of Membrane Separations: Chemical, Pharmaceutical, and Biotechnological Applications, Edited by A. K. Pabby, A. N. Sastre and S. S. H. Rizvi, 01/2009: chapter 11: pages 325-344; CRC Press, Boca Raton, FL.
Rolando Roque-Malherbe: Applications of Natural Zeolites in Pollution Abatement and Industry. In, Handbook of Surfaces and Interfaces of Materials, Volume 5,, Edited by Editor H. S. Nalwa, 12/2001: chapter 12: pages 495-522; Academic Press, San Diego, CA. USA., DOI:10.1016/B(concealed information)/50069-4
Rolando Roque-Malherbe: Dielectric Methods of Research on Zeolites and Related Materials. Handbook of Surfaces and Interfaces of Materials, Volume 2, Edited by Editor H. S. Nalwa, 12/2001: chapter 13: pages 509-531; Academic Press., DOI:10.1016/B(concealed information)/50032-3
Rolando M. A. Roque-Malherbe, M. Hernandez-Velez, F. Fernandez: Dielectric Relaxation in Na-MFI Zeolite. Zeolites and Related Microporous Materials State of the Art 1994, Edited by J. Weitkamp, H. Karge, P. Pfeiffer H. Holderich, 07/1994: chapter 10th International Zeolite Conference. Garmisch-Partenkirchen, Germany, July 17-22, 1994: pages 883-891; Elsevier; Studies in Surface Science and Catalysis. Vol. 84A (1994) 883-891.., DOI:10.1016/S0167-2991(08)64094-X
Rolando M. A. Roque-Malherbe, Luis Lemes: Gas Drying with Natural Zeolites. Zeolites'91 Memoirs of the Third International Conference on Natural Zeolites, Edited by G. Rodriguez, J.A. Gonzalez, 04/1991; International Conference Center Havana Publishing.
R. Roque-Malherbe: Non-conventional Aspects of the Scientific Method. In, Some Problems in the Philosophy of Science, 01/1988; Publishing Department of the Ministry of Higher. Education, Havana, Cuba..
Rolando M. A. Roque-Malherbe: Ethanol production with highly selective acid zeolite catalysts. Simposio Iberiamericano de Catalisis, 01/1986: chapter Congress Chapters: pages 10;
R. Roque-Malherbe: Some Philosophical Concepts Resulting from the Natural Sciences.. In, Philosophy and Science, 01/1985; , “Editorial de Ciencias Sociales”, Havana, Cuba.
R. Roque-Malherbe, L. Lemes, L. López and A. Montes. Physico Chemical parameters for the application of natural zeolites in water adsorption. Zeolites ’93 Full Papers Volume. Editors. D. Ming and F.A. Mumpton. International Committee on Natural Zeolites Press, Brockport, New York, 1995, pp. 299-308.
F. Fernandez, M. HernĂĄndez-VĂ©lez and R. Roque-Malherbe, Dielectric relaxation in Na-MFI zeolite, Studies in Surface Science and Catalysis. Vol. 84A (1994) 883-891. 10th International Zeolite Conference. Garmisch-Partenkirchen, Germany, July 17-22, 1994
M. HernĂĄndez-VĂ©lez and R. Roque-Malherbe.Experimental determination of the dispersion spectrum of zeolites. 6th International Symposium on Electrets. Full Papers Volume, Editors. D.K. Gas-Gupta and A.W. Patullo. IEEE Service Center, Piscataway, N.J. USA., 1988, pp. 576-580. London, September 1988.
G. RodrĂ­guez, C. Lariot Sanchez, R. Roque-Malherbe, R. LĂłpez-Cordero and J.J. GarcĂ­a. Catalyst for ethanol dehydration. X Iberoamerican Catalysis Symposium Full Papers Volume, Andes University, Merida, Venezuela, July 1986, pp. 1287-1298.
G. Rodríguez, C. Lariot-Sanchez, J.C. Romero and R. Roque-Malherbe. Cuban Natural Zeolites. Morphological studies by electron microscopy. Studies in Surface Science and Catalysis Vol. 25 (1985) 275-285. Proceedings of the International Symposium, organized by the “Boris Kidrič” Institute of Chemistry, Ljubljana, on behalf of the International Zeolite Association
G. RodrĂ­guez and R. Roque-Malherbe, Actas Simposio Iberoamericano de Catalysis, Merida, Venezuela, 1986
R. Roque-Malherbe, Some Philosophical Concepts Resulting from the Natural Sciences. In, Philosophy and Science, “Editorial de Ciencias Sociales”, Havana, Cuba, 1985
Patents
16. R. Roque-Malherbe, F. Marquez. Silica mesoporous materials, United States Patent US WO(concealed information), IPC: C01B33/12; C01B33/00 Issued May 1, 2006.
15. R. Roque-Malherbe, W. del Valle, A. Mendoza. System and method for removing heavy metals from water. United States Patent Application Patent Number: S2004/0055958 A1.
14. Rolando M. A. Roque-Malherbe, G. RodrĂ­guez. Procedure for the obtainment of a zeolite acid catalyst from a modified clinoptilolite or heulandite natural zeolite. Patent Certificate No. 22083 ONIITEM, Cuba (1992). Issued May 22, 1992.
13. Rolando M. A. Roque-Malherbe, A. Jacas, M. Hernandez-Velez, E Gonzalez-Aragon. Biocompatible material obtained from a synthetic zeolite. Patent Application Patent solicitude RPI: 61 /91, ONIITEM, Cuba (1991).
12. Rolando M. A. Roque-Malherbe, A. Montes-Carballal. Coupling of thermo-dielectric and thermo-differential analysis. Patent Patent Certificate No. 21922, ONIITEM, Cuba (1990). Issued June 27, 1990.
11. Rolando M. A. Roque-Malherbe, O. Vigil, J. Fundora, H. Villavicencio, M. HernĂĄndez. Solid electrolytes prepared with modified zeolites. Patent Application Patent solicitude RPI: 72/90, ONIITEM, Cuba (1990). ls
10. Rolando M. A. Roque-Malherbe, C. de las Pozas. Synthesis of zeolite A using natural zeolites as raw materials. Patent Application Patent solicitude RPI: 160/89, ONIITEM, Cuba (1989).
9. Rolando M. A. Roque-Malherbe, M. HernĂĄndez-VĂ©lez, O. Raymond, A. Alvarado, A. Jacas, Abrasives from natural zeolites. Patent Application Patent solicitude RPI: 200/89 ONIITEM, Cuba (1989).
8. Rolando M. A. Roque-Malherbe, M. HernĂĄndez-VĂ©lez, O. Raymond, A. Alvarado, A. Jacas. Technical ceramics from natural zeolites. Patent Application Patent solicitude RPI: 38/89 ONIITEM, Cuba (1989).
7. Rolando M. A. Roque-Malherbe, A. Montes, M. Hernandez-Velez and A. Rodriguez-Rivero. Equipment and method for the determination of the dielectric behavior of materials. Patent Certificate No. 21746 ONIITEM, Cuba (1987), Issued April 12, 1988.
6. Rolando M. A. Roque-Malherbe, C de las Pozas. Synthesis of Zeolite X from natural zeolites. Cuba Patent Application Patent solicitude: RPI: 83/87.
5. Inventors: Rolando M. A. Roque-Malherbe, G. Rodriguez, C. HernĂĄndez-Castro and A. Suzarte. Use of furanic resins as gaseous NH3 sorbents Patent Certificate No. 21742 (1987), ONIITEM, Cuba. Issued March 20, 1987.
4. Rolando M. A. Roque-Malherbe, A. Picart and G. Rodriguez. Method of Ni recovery by ionic exchange in natural clinoptilolite. Patent Certificate No. 21503 ONIITEM, Cuba (1985) Issued June 24, 1985.
3. Rolando M. A. Roque-Malherbe, A. Picart, N. Perez and G. Rodriguez. Procedure for Ni extraction by ionic exchange in natural zeolites.. Patent Certificate No. 21055 ONIITEM, Cuba (1982), Issued April 20, 1982.
2. R. Roque-Malherbe, A. Picart, N. Perez and G. Rodriguez. Catalyst obtained by Ni ion exchange of a natural zeolite. Patent Certificate No. 21742 ONIITEM, Cuba (1982).
1. R. Roque-Malherbe, J. C. Antuña, Method of thermodielectric analysis. Patent Certificate No. 21059 ONIITEM, Cuba (1982).

Extended abstracts

43. A. Rios, C. Rivera, R. Polanco, and R. Roque-Malherbe, Structure of a Ni-oxalic metal organic frameworks, 36 Senior ACS meeting, Puerto Rico, December, 2012.
42. C. Lozano, R. Polanco, F. Lugo, A. Hernandez-Maldonado, J. Primera and R. Roque-Malherbe, Adsorption of carbon dioxide on a Cu-nitroprussides polymorph. 43rd World Chemistry Congress, San Juan, PR, August 2011.
41. A. Rios, G. Garcia, L. Fuentes-Cobas and R. Roque-Malherbe, Structure and Magnetic Properties of Ni-oxalic-acid Metal Organic Framework, 43rd World Chemistry Congress, San Juan, PR, August 2011.
40. L. Fuentes-Cobas, S. Nieto, C. Neira, R. Polanco and R. Roque-Malherbe, In-situ XRD high temperature structural study of proton conduction in BaCe0.95Y0.05O3-d and BaCe0.95Yb0.05O3-d perovskites, 43rd World Chemistry Congress, San Juan, PR, August 2011.
39. A. Rios, C. Rivera, R. Polanco, and R. Roque-Malherbe, Synthesis and Adsorption Space of Ni-oxalic-acid Metal Organic Framework, 43rd World Chemistry Congress, San Juan, PR, August 2011.
38. R. Roque-Malherbe, Study of the Interaction between Silica Surfaces and the Carbon Dioxide Molecule, 43rd World Chemistry Congress, San Juan, PR, August 2011.
37. J. A. Santana, F. Diaz-Castro and R. Roque-Malherbe, DFT calculations on the interaction between a simulated silica surface and the carbon dioxide molecule, 43rd World Chemistry Congress, San Juan, PR, August 2011.
36. C. Lozano, R. Polanco, F. Lugo, A. Hernandez-Maldonado and R. Roque-Malherbe Adsorption of carbon dioxide on Ni, Zn-&-Cd-nitroprussides, , 43rd World Chemistry Congress, San Juan, PR, August 2011.
35. A. Costa, C. Rivera, R. Polanco and R. Roque-Malherbe, Study of the Interaction between Dealuminated Natural Clinoptilolites and the Carbon Dioxide Molecule, 43rd World Chemistry Congress, San Juan, PR, August 2011.
34. D. A. Sanchez, N. Ortega, A. Kumar, R. Roque-Malherbe, R. Polanco, J. F. Scott and R. S. Katiyar, Symmetries and Multiferroic Properties of New Room-Temperature Magnetoelectrics: Lead iron tantalate lead zirconate titanate (PFT/PZT), Puerto Rico ACS Junior Meeting and Interdisciplinary Scientific Meeting, Interamerican University, PR, 2011, p. 331.
33. F. Marquez-Linares, O. Uwakweh, N. Lopez, E. Chavez, R. Polanco , C. Morante, J. M. Sanz, E. Elizalde, C. Neira, S. Nieto and R. Roque-Malherbe, Study of the surface chemistry and morphology of single walled carbon nanotube (SWCNT)-magnetite composites, NanoTech 2010, Anaheim, CA, June 2010.
32. F. Marquez, R. Roque-Malherbe, O. Uwakweh, C. Morant, T. Campo and E. Elizalde, and, Synthesis and characterization of chemically modified carbon nanotubes, Diamond 2010, Budapest, Hungary, September, 2010.
31. E. Calderón‐Ortiz, F. Márquez, R. Roque‐Malherbe, C. Morant, T. Campo, J.M. Sanz, Ferrite functionalized carbon nanotubes and their reponse to magnetic fields, Diamond 2009, Athens, Greece, September 6-10, 2009.
30. R. Roque-Malherbe and V. Ivanov, Diffusion, Codiffusion and Counterdiffusion of para-xylene and ortho-xylene in a Zeolite with 10 MR/12 MR Interconnected Channels. An Example of Molecular Traffic Control. Diffusion in Solids and Liquids 2009, Rome, Italy, June 23-26, 2009.
29. R. Roque-Malherbe, F. Marquez, W. del Valle and M. Thommes, Synthesis and Characterization of High Specific Surface Area Nanostructured Silica Materials for Hydrogen Storage and Other Applications. MOLMAT 2008. Third International Sysmposium of Molecular Materials, Toulouse, France, July, 2008.
28. R. Roque-Malherbe, M. C. Cotto, S. Nieto and J. Duconge, Mechanocatalytic Decomposition of Phenol, IUPAC-XXVIII Latin American Congress of Chemistry, San Juan PR, USA, August, 2008.
27. C. Muñiz, F. Diaz and R. Roque-Malherbe,Dynamic Adsorption of para-, l meta- and ortho-nitrophenol from Aqueous Solutions in DAY zeolite.IUPAC-XXVIII Latin American Congress of Chemistry, San Juan PR, USA, August, 2008.
26. R. Roque-Malherbe and F. Marquez.Synthesis and Characterization of Silica Sphere-Packing Mesoporous Materials, 26th Symposium on Applied Surface Analysis, Pacific Northwest National Laboratory, Richland, Washington, June 2004.
25. F. Marquez and R. Roque-Malherbe, Synthesis and Characterization of New Opal Based Materials, European Materials Research Society 2004 Meeting. Symposium-C, Strasbourg, France, May 2004
24. F. MĂĄrquez, J. DucongĂ©, W. del Valle and R. Roque-Malherbe, Polymerisation of aniline in the channels of micro and mesoporous materials, ECASIA’03, Berlin Germany, October, 2003.
23. R. Roque-Malherbe, W. del Valle, N. Planas, K. Gómez, D. Ledes, L. Garay and J. Ducongé Study of Pb2+, Ni2+, Co2+ and Cu2+ Removal from Water Solutions by Dynamic Ionic Exchange, in Na-Clinoptilolite Beds.
Zeolites '02 Book of Abstracts (P. Misaelides Ed.) 7th International Conference on the Occurrence, Properties and Use of Natural Zeolites, Thessaloniki, Greece, June 3-7, 2002. pp. 316-317.
22. R. Roque-Malherbe, D. Ledes, W. del Valle, J. Ducongé, S. Segarra and C. Feliciano. Adsorbent Materials Obtained from the Hydrothermal Transformation of Clinoptilolite, Zeolites '02 Book of Abstracts (P. Misaelides Ed.) 7th International Conference on the Occurrence, Properties and Use of Natural Zeolites, Thessaloniki, Greece, June 3-7, 2002. pp. 313-315.
21. R. Roque-Malherbe, W. del Valle, N. Planas, K. Gomez and J. Duconge. Study of Pb2+, Ni2+, Co2+ and Cu2+ dynamic ionic exchange in Na-clinoptilolite beds, Abstracts Volume of the 13th EPSCoR AAAS Annual Meeting, Hyatt Regency Cerromar, Dorado, PR April 20-22, 2001.
20. R Roque-Malherbe. Synthesis and characterization of a FAPO-5 molecular sieve Abstracts Volume of the 12th AAAS and EPSCoR Annual Meeting, Windham "El Coquistador" Resort and Country Club, Fajardo, PR May, 26-28, 2000.
19. R. Roque-Malherbe and D. Ledes, Adsorbents obtained from the phase transformation of a natural zeolite. Abstracts Volume of the 12th AAAS and EPSCoR Annual Meeting, Windham "El Conquistador" Resort and Country Club, Fajardo, PR May, 26-28, 2000.
18. R. Sanchez, D. Ledes and R. Roque-Malherbe. Adsorption calorimetry of NH3 in a FAPO-5 molecular sieve. XXIII Latin American Congress of Chemistry Extended Abstracts Volume, Westin Rio Mar Hotel, Puerto Rico, July, 26-31, 1998.
17. R. Roque-Malherbe. Pollution abatement applications of natural zeolites, 5th Caribbean Environmental Chemical Conference. Invited Paper. Westin Rio Mar Hotel, Puerto Rico, August 1997.
16. R. Wendelbo and R. Roque-Malherbe. A comparative study of the kinetics of adsorption of benzene and o-xylene in H-MCM-22, H-ZSM-5 and H-Beta zeolites. Nordic Catalysis Symposium, Finland, 1996
15. R. Roque-Malherbe, R. Wendelbo, A. Mifsud and . A. Corma. Difusion de hidrocarburos en zeolitas H-ZSM-5, H-Beta y H-MCM-22. Reunión Anual del Grupo Especializado de Catålisis, CSIC, Peñiscola, Spain, 1995
14. R. Roque-Malherbe. Applications of Natural Zeolites. 11th Reunion du Groupe Francais des Zeolithes, Lac Chambon, France, 1995.
13. C. de las Pozas, R. Lopez-ordero and R. Roque-Malherbe. Hydrogenation of hexene and benzene with a Ni-clinoptilolite catalyst. Zeolite ’95 Extended Abstract Volume. Natural Zeolite International Conference. Sofia, Bulgaria, June 1995.
12. R. Roque-Malherbe, M. Carreras-Gracial and J. Onate-Martinez. Synthesis and characterization of a CaAPO-5 molecular sieve. 9th International Zeolite Conference Recent Research Reports Volume, International Zeolite Association, Montreal, 1992. 9th IZC, Montreal, Canada, July 1992
11. H. Villavicencio, M. Hernandez-Velez, O. Vigil-Galan, A. Rodriguez-Rivere, R. Roque-Malherbe, M. Betancourt and A. Diaz. Natural zeolites as component of dry-cell electrolyte. Zeolites '91 Abstracts Volume. Editors. G. RodrĂ­guez and J.A: GonzĂĄlez. International Conference Center Press, Havana, 1992, 3rd International Conference on the Occurrence, Properties and Use of Natural Zeolites. Havana, Cuba, April 1991.
10. R. Roque-Malherbe, L. LĂłpez-Colado, C. GonzĂĄlez, M. HernĂĄndez- VĂ©lez, C. de las Pozas del Rio, M. Carreras and A. Montes. Zeolite analytics. Zeolites '91 Abstracts Volume. Editors. G. RodrĂ­guez and J.A: GonzĂĄlez. International Conference Center Press, Havana, 1992, 3rd International Conference on the Occurrence, Properties and Use of Natural Zeolites. Havana, Cuba, April 1991.
9. R. Roque-Malherbe, J. de Onate, J. Fernandez and C. DĂ­az. Tribochemical reactions in zeolites. Zeolites '91 Abstracts Volume.. Editors. G. RodrĂ­guez and J.A: GonzĂĄlez. International Conference Center Press, 3rd International Conference on the Occurrence, Properties and Use of Natural Zeolites. Havana, Cuba, April 1991.
8. M. Hernandez-Velez, R. Roque-Malherbe, O. Raymond-Herrera, A. Jacas, Rodriguez, A. Alvarado-Martin and L. Hidalgo. Natural zeolite phase transformations at high temperature. Zeolites '91 Abstracts Volume.. Editors. G. RodrĂ­guez and J.A: GonzĂĄlez. International Conference Center Press, 3rd International Conference on the Occurrence, Properties and Use of Natural Zeolites. Havana, Cuba, April 1991.
7. L. Lemes-Fernandez, R. Roque-Malherbe and A. Montes-Carballal. Physico-Chemical study of CO2 drying with natural zeolites. Zeolites '91 Abstracts Volume. Editors. G. RodrĂ­guez and J.A: GonzĂĄlez. International Conference Center Press, 3rd International Conference on the Occurrence, Properties and Use of Natural Zeolites. Havana, Cuba, April 1991.
6. F. Benitez, L. Travieso, E. Sanchez and R. Roque-Malherbe. Waste water treatment technology. International Conference on Advanced Waste Water Treatment and Reclamation, Cracow, Poland, September, 1989.
5. L. Lemez, A. Montes, O. Herrera and R. Roque-Malhebe. Technological parameters for the application of natural zeolites as water adsorbents. 8th International Zeolite Conference Recent Research Reports Volume, International Zeolite Association, Amsterdam, 1989.
4. R. Roque-Malherbe, C. de las Pozas and J. Castillo-Santana. Dielectric differential thermal analysis of faujasite. 7th International Zeolite Conference Preprints of Poster Papers Volume , Japan Zeolite Association, Tokyo, 1986. Tokyo. Japan, August 1986, 4B-73. M. Hernandez-Velez and R. Roque-Malherbe
3. M. Hernandez-Velez and R. Roque-Malherbe,Dielectric spectrometry of Na and Ca clinoptilolite. 7th International Zeolite Conference Preprints of Poster Papers Volume , Japan Zeolite Association, Tokyo, 1986. Tokyo. Japan, August 1986, 4B-5
2. R. Roque-Malherbe, A. Berazain and J. del Rosario. Calorimetry of ionic exchange in natural zeolites, 7th International Zeolite Association Conference Preprints of Poster Papers Volume, Japan Zeolite Association, Tokyo, 1986. Tokyo. Japan, August 1986
1.G. Rodriguez, R. Lopez-Cordero, C. Lariot and R. Roque-Malherbe.. Physico-chemical properties of natural clinoptilolite. Zeolite '85 Program and Abstracts Volume. 2nd International Conference on the Occurrence, Properties and Use of Natural Zeolites. International Committee on Natural Zeolites, Budapest, Hungary, August 1985.


Journal Publications
Amal Suleiman, Yaritza HernĂĄndez-LebrĂłn, Maxime J.-F. Guinel, Rolando Roque-Malherbe, Carlos Raul Cabrera: Rotating Disk Slurry Electrodeposition of Platinum at ZSM-5/Carbon Vulcan XC-72R for Methanol Oxidation in Alkaline Media. In progress to be submitted
Rolando M. A. Roque-Malherbe, C, Rivera F. Lugo and R. Polanco: Adsorption of carbon dioxide on a Cu-Succinic metal organic framework, submitted to Revista de Ingenieria Global, Chile.
R. Roque-Malherbe, F. Lugo, R. Polanco: Synthesis, structural elucidation and carbon dioxide adsorption on Zn (II) hexacyanoferrate (II) Prussian blue analogue. Applied Surface Science 05/2016; 385., DOI:10.1016/j.apsusc.2016.04.139
R. Roque-Malherbe, E. Carballo, R. Polanco, F. Lugo, C. Lozano: Structure and adsorption properties of a porous cooper hexacyanoferrate polymorph. Journal of Physics and Chemistry of Solids 05/2015; 86., DOI:10.1016/j.jpcs.2015.04.009
R. Roque-Malherbe, F. Lugo, C. Rivera-Maldonado, R. Polanco-Estrella, O. Uwakweh: Synthesis, characterization and thermodynamic study of carbon dioxide adsorption on akaganéite. Current Applied Physics 04/2015; 15(4)., DOI:10.1016/j.cap.2015.01.016
Amal Suleiman, Christian L. Menéndez, Ramon Polanco, Esteban Rosim Fachini, Yaritza Hernåndez-Lebrón, Maxime J.-F. Guinel, Rolando Roque-Malherbe, Carlos Raul Cabrera: Rotating Disk Slurry Electrodeposition of Platinum at Y-Zeolite/Carbon Vulcan XC-72R for Methanol Oxidation in Alkaline Media. RSC Advances 12/2014; 5(10)., DOI:10.1039/C4RA05877A
R. Roque-Malherbe, S. Nieto, R.S. Katiyar, R. Polanco-Estrella, P. Fierro, C. Lozano: High temperature proton transport in BaCe0.95Yb0.05O3−ή perovskite. Ceramics International 08/2014; 40(7)., DOI:10.1016/j.ceramint.2014.03.076
Rolando Roque-Malherbe: Study of the adsorption space of modified clinoptilolites, Journal of Materials Science & Engineering A Vol. 3 (2013) 263-280.
Rolando M. A. Roque-Malherbe: Media portrayal of scientists. Chemical & Engineering News 07/2012; 90:2.
D. A Sanchez, N. Ortega, Ashok Kumar, R Roque-Malherbe, R Polanco, R. S Katiyar, J. F. Scott: A New Room-Temperature Multiferroic: Lead Iron Tantalate Zirconate Titanate. 01/2012; Vol. 1(S1):27-33., DOI:10.1680/emr.2012.1.S1.004
R. Roque-Malherbe: Synthesis, structure, adsorption space and magnetic properties of Ni-oxalate porous molecular magnet. Journal of Materials Science & Engineering A Vol. 2 (2012) 284-301.
Dilsom A. Sanchez, N. Ortega, Ashok Kumar, R. Roque-Malherbe, R. Polanco, J. F. Scott, Ram S. Katiyar: Symmetries and multiferroic properties of novel room-temperature magnetoelectrics: Lead iron tantalate - Lead zirconate titanate (PFT/PZT). AIP Advances 12/2011; 1(4)., DOI:10.1063/1.3670361
R. Roque-Malherbe, O.N.C. Uwakweh, C. Lozano, R. Polanco, A. Hernandez-Maldonado, P. Fierro, F. Lugo, J. N. Primera-Pedrozo: Structural Effects and Interactions of Carbon Dioxide Molecules Adsorbed on Ni, Zn, and Cd Nitroprussides. The Journal of Physical Chemistry C 07/2011; 115(31)., DOI:10.1021/jp205104r
R. Roque-Malherbe, C. Lozano, R. Polanco, F. Marquez, F. Lugo, A. Hernandez-Maldonado, J.N. Primera-Pedrozo: Study of carbon dioxide adsorption on a Cu-nitroprusside polymorph. Journal of Solid State Chemistry 05/2011; 184(5):1236-1244., DOI:10.1016/j.jssc.2011.02.029
Francisco Mårquez, Teresa Campo, María Cotto, Ramón Polanco, Rolando Roque, Pedro Fierro, José María Sanz, Eduardo Elizalde, Carmen Morant: Synthesis and Characterization of Monodisperse Magnetite Hollow Microspheres. Soft Nanoscience Letters 04/2011; 1(2):25-32., DOI:10.4236/snl.2(concealed information)
F. Marquez-Linares, O. N. C. Uwakweh, N. Lopez, E. Chavez, R. Polanco, C. Morant, J. M. Sanz, E. Elizalde, C. Neira, S. Nieto, R. Roque-Malherbe: Study of the surface chemistry and morphology of single walled carbon nanotube–magnetite composites. Journal of Solid State Chemistry 03/2011; 184(3):655-666., DOI:10.1016/j.jssc.2011.01.017
R. Roque-Malherbe, R. Polanco-Estrella, F. Marquez-Linares: Study of the Interaction between Silica Surfaces and the Carbon Dioxide Molecule. The Journal of Physical Chemistry C 09/2010; 114:17773., DOI:10.1021/jp107754g
MĂĄrquez Francisco, LĂłpez Vicente, Morant Carmen, Roque-Malherbe Rolando, Domingo ConcepciĂłn, Elizalde Eduardo, Zamora FĂ©lix: Structure and Characterization of Vertically Aligned Single-Walled Carbon Nanotube Bundles. Journal of Nanomaterials 09/2010; 2010(6348)., DOI:10.1155/2010/189214
R. Roque-Malherbe: Structure and Characterization of Vertically Aligned Single-walled Carbon Nanotube Bundles. Journal of Nanomaterials (2010) Article ID: 189214, 7 pages doi:10.1155/2010/189214.
R. Roque-Malherbe, V. Ivanov: Codiffusion and counterdiffusion of para-xylene and ortho-xylene in a zeolite with 10 MR/12 MR interconnected channels. An example of molecular traffic control. Journal of Molecular Catalysis A Chemical 11/2009; 313(1):7-13., DOI:10.1016/j.molcata.2009.07.01
M.C. Cotto, A Emiliano, S Nieto, J Duconge, R Roque-Malherbe: Degradation of phenol by mechanical activation of a rutile catalyst. Journal of Colloid and Interface Science 09/2009; 339(1):133-9., DOI:10.1016/j.jcis.2009.07.016
R Roque-Malherbe, F Marquez-Linares, W Del Valle, M Thommes: Ammonia Adsorption on Nanostructured Silica Materials for Hydrogen Storage and Other Applications. Journal of Nanoscience and Nanotechnology 12/2008; 8(11):5993-6002., DOI:10.1166/jnn.2008.335
C Muñiz-Lopez, J Duconge, R Roque-Malherbe: Paranitrophenol liquid-phase adsorption in dealuminated Y zeolite. Journal of Colloid and Interface Science 10/2008; 329(1):11-6., DOI:10.1016/j.jcis.2008.09.051
R. Roque-Malherbe: Calculation of the Energy of Adsorption of n-Paraffins in Nanoporous Crystalline and Ordered Acid Catalysts, and its Relationship with the Activation Energy of the Monomolecular Catalytic Cracking Reaction. Journal of Molecular Catalysis 01/2008; 280:194-202.
R. Roque-Malherbe, W. del Valle, F. Marquez, J. Duconge and M.F.A. Goosen, Synthesis and Characterization of Zeolite Based Porous Ceramic Membranes, Separation Science and Technology Vol. 41 (2006) 73-96
Santander Nieto, RamĂłn Polanco, Rolando Roque-Malherbe: Absorption Kinetics of Hydrogen In Nanocrystals of BaCe0.95Yb0.05O3-ÎŽ Proton-Conducting Perovskite. The Journal of Physical Chemistry C 01/2007; 111(6)., DOI:10.1021/jp067389i
R. Roque-Malherbe: Lead, copper, cobalt and nickel removal from water solutions by dynamic ionic exchange in leca zeolite beds. International Journal of Environment and Pollution 01/2007; 31:292-303..
Francisco Marquez-Linares, Rolando M A Roque-Malherbe: Synthesis and Characterization of Large Specific Surface Area Nanostructured Amorphous Silica Materials. Journal of Nanoscience and Nanotechnology 05/2006; 6(4):1114-8., DOI:10.1166/jnn.2006.166
J. Duconge and R. Roque-Malherbe: The Role of Physical Theories, Glosa.
Rolando Roque-Malherbe, Francisco Marquez: Synthesis and characterization of silica sphere‐packing mesoporous materials. Surface and Interface Analysis 04/2005; 37(4):393 - 397., DOI:10.1002/sia.2011
R. Roque-Malherbe, F. Marquez: Synthesis and characterization of silica microsphere-based mesoporous materials. Materials Science in Semiconductor Processing 08/2004; 7(4):467-469., DOI:10.1016/j.mssp.2004.09.092
F. MĂĄrquez, R. Roque‐Malherbe, J. DucongĂ©, W. del Valle: Polymerization of aniline in the channels of micro‐ and mesoporous materials. Surface and Interface Analysis 08/2004; 36(8):1060 - 1063., DOI:10.1002/sia.1837
R. Roque-Malherbe: Zeolites. Part 2, Facets, IUMRS Journal Vol. 3, No. 1 (2004) 8-11
Rolando Roque Malherbe, Rune Wendelbo: Study of Fourier transform infrared-temperature-programmed desorption of benzene, toluene and ethylbenzene from H-ZSM-5 and H-Beta zeolites. Thermochimica Acta 04/2003; 400(1):165-173., DOI:10.1016/S0040-6031(02)00488-4
R. Roque-Malherbe: Zeolites. Part 1. Structural Features, Synthesis, Modification and Characterization, Facets-IUMRS Journal Vol 2 No. 4 (2003) 14-17.
R. Roque-Malherbe: Letter to the Editor Study of Diffusion and Counter-diffusion of Para and Ortho Xylene in H-SSZ-24 and H-ZSM-11 Zeolites. Microporous and Mesoporous Materials 01/2002; 56:321-324.
Rolando Roque-Malherbe, Vasily Ivanov: Study of diffusion and counter-diffusion of para- and ortho-xylene in H-SSZ-24 and H-ZSM-11 zeolites. Microporous and Mesoporous Materials 09/2001; 47(1-47):25-38., DOI:10.1016/S1387-1811(01)00320-1
R. Roque-Malherbe: Complementary Approach to the Volume Filling Theory of Adsorption. Microporous and Mesoporous Materials 01/2000; 41:227-240.
German Sastre, Nilesh Raj, C. Richard A. Catlow, Rolando Roque-Malherbe, Avelino Corma: Selective Diffusion of C8 Aromatics in a 10 and 12 MR Zeolite. A Molecular Dynamics Study. The Journal of Physical Chemistry B 02/1998; 102(17):3198-3209., DOI:10.1021/jp980053r
Rune Wendelbo, Rolando Roque-Malherbe: A comparative study of the kinetics of adsorption and desorption of benzene and o-xylene in H-MCM-22-, H-ZSM-5- and H-beta-zeolites. Microporous Materials 07/1997; 10(4):231-246., DOI:10.1016/S0927-6513(97)00014-X
R. Roque-Malherbe: A comparative study of the kinetics of adsorption of benzene and o-xylene in H-MCM-22, H-ZSM-5 and H-Beta zeolites. Microporous Materials 01/1997; 10 (1997) 231-246.:231-246..
Hernandez-Velez M, A.Jacas RodrĂ­guez, Gonzalez Aragon E, Roque-Malherbe R, Onate-Martinez J: Synthesis and characterization of molecular sieve with AlPO4-5 framework. Preliminary biomedical essays. Materials Letters 10/1996; 28(4):507-511., DOI:10.1016/0167-577X(96)00105-X
R. Roque-Malherbe: Modification of clinoptilolite by ortophosphoric acid leaching .. Microporous Materials 01/1996; 5:325-331.
R. Roque-Malherbe: Endless zeolite deposits, CUBANEWS. Miami Herald Pub. Co., Vol.4(12) (1996) 10-10.
M. Hernandez-Velez, O. Raymond-Herrera, A. Alvarado-Martin, A. Jacas-Rodriguez, R. Roque-Malherbe: New materials obtained from high temperature phase transformations of natural zeolites. Journal of Materials Science Letters 12/1995; 14(23):1653-1656., DOI:10.1007/BF(concealed information)
Rolando Roque-Malherbe, Rune Wendelbo, Amparo Mifsud, Avelino Corma: Diffusion of aromatic hydrocarbons in H-ZSM-5, H-Beta, and H-MCM-22 zeolites. The Journal of Physical Chemistry 04/1995; 99:14(concealed information), DOI:10.1021/j100038a043
C. de las Pozas, C. Diaz-Aguila, M.C.D.A. Cora, R. Lopez-Cordero, R. Roque-Malherbe: Location and Reducibility of Ni Ions in HEU-Type Zeolites. Journal of Solid State Chemistry 01/1995; 114(1)., DOI:10.1006/jssc.1995.1016
R. Roque-malherbe, R. Wendelbo, A. Mifsud, A. Corma: Diffusion of aromatic hydrocarbons in H-ZSM-5, H-beta, and H-MCM-22 zeolites. The Journal of Physical Chemistry 01/1995; 99(14(concealed information))., DOI:10.1002/chin.(concealed information)
R. Roque-Malherbe: Dielectric properties of zeolite materials. Boletin de la Sociedad Espanola de Ceramica y Vidrio 01/1995; 34:409-413.
M. Hernandez-Valez, R. Roque-Malherbe: Dielectric relaxation in hydrated natural mordenite. Journal of Materials Science Letters 12/1994; 14(16):1112-1114., DOI:10.1007/BF(concealed information)
R. Roque-Malherbe, J. DE Onate-Martinez, E. J. Navarro: Furfural oligomerization within H-Fe-FAU zeolite. Journal of Materials Science Letters 07/1993; 12(13):1037-1038., DOI:10.1007/BF(concealed information)
C. de las Pozas, R. Lopez-Cordero, J. A. Gonzalez-Morales, N. Travieso, R. Roque-Malherbe: Effect of pore diameter and acid strength in ethanol dehydration on molecular sieves. Journal of Molecular Catalysis 07/1993; 83(1-2):145-156., DOI:10.1016/0304-5102(93)87015-Z
R. Roque-Malherbe, R. Lopez-Cordero, J.A. Gonzales-Morales, J. Oñate-Martinez, M. Carreras-Gracial: A comparative study of MeAPO molecular sieves with AFI structure type. Zeolites 07/1993; 13(6-13):481-484., DOI:10.1016/0144-2449(93)90124-L
R. Roque, J. de Onate, E. Reguera, E. Navarro: Pyrrole oligomerization within H-Fe-FAU zeolite. Journal of Materials Science 01/1993; 28(9):2321-2323., DOI:10.1007/BF(concealed information)
J. de Oñate Martínez, C. Díaz Aguila, J. Fernåndez Bertrån, E. Reguera Ruíz, C. Portilla Vergara, R. Roque Malherbe: Tribochemical reactions of erionite and Na-LTA zeolites with Fe 2 (SO 4 ) 3 .5H 2 O: A mössbauer study. Hyperfine Interactions 10/1992; 73(3):371-375., DOI:10.1007/BF(concealed information)
O. Vigil, J. Fundora, H. Villavicencio, M. Hernandez-Velez, R. Roque-Malherbe: Direct-current transport phenomena in Na-FAU zeolite. Journal of Materials Science Letters 01/1992; 11(24):1725-1727., DOI:10.1007/BF(concealed information)
E. Reguera, Carlos de las Pozas-Del Río, Carlos Díaz-Aguila, Rolando Roque-Malherbe: Mössbauer study of hydrothermal transformation of natural clinoptilolite into Y and P1 zeolites. Journal of Solid State Chemistry 10/1991; 94(2):215-219., DOI:10.1016/0022-4596(91)90185-K
R. Roque-Malherbe, C. de las Pozas, M. Carreras: Dielectric differential thermal analysis. Journal of Thermal Analysis and Calorimetry 10/1991; 37(10):2423-2425., DOI:10.1007/BF(concealed information)
R. Gonzales-Santos, R. Roque-Malherbe: Dielectric differential thermal analysis - Part VIII. Dithionates. Journal of Thermal Analysis 04/1991; 37(4)., DOI:10.1007/BF(concealed information)
R. Roque-Malherbe, M. Carreras, C. de las Pozas: Thermodielectric Analysis. Part 9. The role of guest molecules.. Journal of Thermal Analysis 01/1991; 37:2423-2425.
R. Roque-Malherbe: Mössbauer study of the hydrothermal transformation of clinoptilolite in faujasite.. Journal of Solid State Chemistry 01/1991; 93:215-219.
R. Roque-Malherbe: Structural comparison of clinoptilolite and heulandite.. Journal of the Chemical Society Abstracts 01/1991; Vol. 119(No. 99985k.).
E. Sastre, J. PĂ©rez-Pariente, A.Corma, R. Roque-Malherbe and C. de las Pozas., Measurement of the morphology and size of zeolites cavities by m-xylene isomerization, Revista CNIC. Ciencias QuĂ­micas Vol.21 (1991) 225-228.
R. Roque-Malherbe, M. Hernandez-Velez: Foundations of thermo-dielectrical analysis. Part I. J, Thermal Analysis, 11/1990; 36(7-8):2455-2464., DOI:10.1007/BF(concealed information)
E. Reguera, Rolando Roque-Malherbe, Carlos DĂ­az-Aguila, Juan Fundora-Lliteras, Lazaro LĂłpez-Colado, Manuel HernĂĄndez-Velez: The State of Iron in Natural Zeolites: A Moessbauer Study. Zeolites 09/1990; 19(7):685-689., DOI:10.1016/0144-2449(90)90080-B
Jose Fernåndez-Bertran, Rolando Roque Malherbe: Tribochemical reaction between Na-FAU and AlPO4 · 3H2O. Reactivity of Solids 06/1990; 8(1-2):141-145., DOI:10.1016/0168-7336(90)80014-B
R. Roque-Malherbe, M. Hernandez-Velez: Foundations of thermo-dielectrical analysis. Part 2. Calculation of the dielectric suscepribility. Journal of Thermal Analysis 05/1990; 36(3):2445-2464., DOI:10.1007/BF(concealed information)
R. Roque-Malherbe, C. Dueñas, L. Lemes-Fernandez: Study of the dynamic adsorption of water vapor in gas mixtures. Part I.. Revista CNIC. Ciencias Químicas. Vol. 21 (1990) 166-167
R. Roque-Malherbe: Study of the dynamic adsorption of water vapor in gas mixtures. Part II. Revista CNIC. Ciencias QuĂ­micas Vol.21 (1990) 168-169.
R. Roque-Malherbe: Perspectives of the use of natural zeolites in aquaculture. Revista CNIC. Ciencias QuĂ­micas Vol.21 (1990) 223-224.
J. De la Cruz, C. Rodriguez, R. Roque-Malherbe: Model description of molecular adsorption in zeolites. Surface Science Letters 02/1989; Volume 209, Issues 1–2,., DOI:10.1016/0167-2584(89)90606-3
Mercedes Fuentes, Juan Magraner, Carlos De Las Pozas, Rolando Roque-Malherbe, JoaquĂ­n PĂ©rez Pariente, Avelino Corma: Cyclization of Citronellal to Isopulegol by Zeolite Catalysis. Applied Catalysis 02/1989; 47(2-47):367-374., DOI:10.1016/S0166-9834(00)83242-X
Carlos de las Pozas, David DĂ­az Quintanilla, Joaquin PĂ©rez-Pariente, Rolando Roque-Malherbe, M. Magi: Hydrothermal transformation of natural clinoptilolite to zeolites Y and P1: Influence of the Na, K content. Zeolites 01/1989; 9(1):33-39., DOI:10.1016/0144-2449(89)90006-7
R. Roque-Malherbe: Thermodielectric analysis. Part 7. Kaolins.. Journal of Thermal Analysis 01/1989; 35:1359-1364.
R. Roque-Malherbe, C. de las Pozas, M. Carreras: Dielectric-differential thermal analysis - Part V: The role of cationic conduction. J Thermal Analysis Journal of Thermal Analysis Vol.34 (1988) 1113-1115
DOI:10.1007/BF(concealed information)
J. A. Alonso PĂ©rez, R. Roque-Malherbe, C. R. GonzĂĄlez GonzĂĄlez, C. de las Pozas: Thermodielectrical analysis - VI. Bentonites. Journal of Thermal Analysis 05/1988; 34(3):865-870., DOI:10.1007/BF(concealed information)
Rolando M. A. Roque-Malherbe: Complementary remarks to the thermodynamics of adsorption in microporous solids. Revista Cubana de Fisica 01/1988; 8:91-94.
M. Hernandez-Velez, R. Roque-Malherbe: Dielectric spectrometry of Na and Ca clinoptilolite and mordenite. Journal of the Chemical Society Abstracts 01/1988; Vol. 110.(No. 184128s).
R. Roque-Malherbe: Physico-chemical properties of a faujasite obtained by hydrothermal transformation, Revista CNIC. Ciencias QuĂ­micas Vol. 19 (1988) 43-46
R. Roque-Malherbe: Kinetics of the hydrothermal transformation of Na-HEU, Revista CNIC. Ciencias QuĂ­micas Vol. 19 (1988) 40-42
C. R. Gonzalez, R. Roque: Optimization of quantitative X-ray phase analysis by Monte Carlo methods. Acta crystallographica. Section A, Foundations of crystallography 09/1987; 43(5):622-626., DOI:10.1107/S(concealed information)098829
R. J. Roque-Malherbe: Solution thermodynamics of adsorption in microporous adsorbents. Journal of Thermal Analysis 09/1987; 32(5):1361-1367., DOI:10.1007/BF(concealed information)
E. Sanchez, R. Roque-Malherbe: Zeolite as supoport material in anaerobic wastewater treatment. Biotechnology Letters 09/1987; 9(9):671-672., DOI:10.1007/BF(concealed information)
R. Roque-Malherbe, R. Delgado, C. Contreras, A. Lago: Behaviour of yeast fermentation in the presence of zeolite. Biotechnology Letters 09/1987; 9(9):640-642., DOI:10.1007/BF(concealed information)
M. Carreras, R. Roque-Malherbe, C. de las Pozas: Dielectric-differential thermal analysis IV the role of water. Journal of Thermal Analysis and Calorimetry 07/1987; 32(4):1271-1276., DOI:10.1007/BF(concealed information)
C. R. GonzĂĄlez, R. Roque-Malherbe, E. D. Shchukin: Theoretical principles for quantitative X-ray analysis in systems with high microabsorption. Journal of Materials Science Letters 05/1987; 6(5):604-606., DOI:10.1007/BF(concealed information)
R. Roque-Malherbe, A. Berazain and J.A. del Rosario, Calorimetric measurement of ion exchange heats in homoinic heulandite and mordenite, Journal of Thermal Analysis Vol. 32 (1987) 949-951
M. Autie and R. Roque-Malherbe, Adsorption of atmospheric gases in a natural zeolite, Revista Tecnologica Vol. 27 (1987) 949-951.
R. Roque-Malherbe, Properties smoothing in surfaces property, Revista Cubana de FĂ­sica Vol. 7 (1987) 83-84
R. Roque-Malherbe: Dielectric differential thermal analysis. Part 3.. Journal of Thermal Analysis 01/1987; 32:321-323..
R. Roque-Malherbe: Thermodielectric analysis. Part 2. Zeolites.. Journal of Thermal Analysis 01/1986; 16:517-521.
A. Montes, R. Roque-Malherbe, E. D. Shchukin: Dielectric-differential thermal analysis part I: Method. Journal of Thermal Analysis 01/1986; 31(1)., DOI:10.1007/BF(concealed information)
G.Rodriguez Fuentes, C.Lariot Sanchez, J.C. Romero, R.Roque Malherbe: Cuban Natural Zeolites: Morphological Studies by Electron Microscopy. Studies in surface science and catalysis 12/1985; 24:375-384., DOI:10.1016/S0167-2991(08)65304-5
R. Roque-Malherbe, L.LĂłpez-Colado, C. de las Pozas, V. Zelenenko: Determination of the differential heat of adsorption in homoionic zeolites. Part II. Journal of the Chemical Society Abstracts 01/1985; Vol. 105(No. 181437b).


L.LĂłpez-Colado, C. de las Pozas, R. Roque-Malherbe and V. Zelenenko. Measurement of the differential heat of adsorption in homoionic zeolites. Part I Revista Cubana de FĂ­sica Vol. 5 (1985) 124-127. Chemical Abstracts Vol. 105 No. 232827q
L.LĂłpez-Colado, C. de las Pozas, R. Roque-Malherbe and V. Zelenenko. Determination of the differential heat of adsorption in homoionic zeolites. Part II Revista Cubana de FĂ­sica Vol. 5 (1985) 128-130. Chemical Abstracts Vol. 105 No. 181437b
L. LĂłpez-Colado and R. Roque-Malherbe, Quantitative analysis of zeolites by physical methods, Revista Varona Vol. 7 (1985) 167-180
R. Roque-Malherbe, O. Figueroa and C. Lariot, Laboratory adsorption lyophilizer, Revista CNIC. Ciencias QuĂ­micas Vol. 16 (1985) 73-77, Chemical Abstracts Vol. 107 No. 178739p
M. Autie and R. Roque-Malherbe, Gas chromatographic study of the adsorption heats of natural gas components on natural and acid decationized zeolites, Revista CNIC. Ciencias QuĂ­micas Vol.16 (1985) 129-136, Chemical Abstracts Vol. 107 No. 99357j
R. Roque-Malherbe and J.C. Antuña , Dielectric thermal analysis method, Revista CNIC. Ciencias Químicas Vol.16 (1985) 89-103, Chemical Abstracts Vol. 107 No. 142519c
R. Roque-Malherbe, C. de las Pozas, and G. Rodriguez, Effect of Ion exchange in the Adsorption of NH3 and CO2 on Natural Clinoptilolite, Revista Cubana de Fisica Vol. 4 (1984) 143–147, Chemical Abstracts Vol. 103 No. 22139
R. Roque-Malherbe, A. Picart, M. Autie, J.A. Sosa-Cuervo and M. Hernandez-Velez , Thermodynamics study of gas and vapor adsorption of gases on natural zeolites. KINAM Vol. 6 (1984) 101-114. Chemical Abstracts Vol. 102 No. 173067c.
A. Perez-Reyes, C. Diaz and R. Roque-Malherbe, Interdiffussion of Nickel and Carbon steel, Revista de Metalurgia CENIM Vol. 20 (1984) 343-348 , Chemical Abstracts Vol. 102 No. 153010a.
R. Roque-Malherbe, Thermodynamics of the adsorption of gases in microporous solids, KINAM Vol. 6 (1984) 23-33. Chemical Abstracts Vol. 102 No. 85228c.
R. Roque-Malherbe, Statistical thermodynamics of physical adsorption on zeolites, KINAM Vol. 6 (1984) 135-131., Chemical Abstracts Vol. 102 No.67816p.
R. Roque-Malherbe, M. Autie and A. Picart, Adsorption of gases on Cuban natural zeolites,Rev. CNIC Ciencias Quimicas Vol.15 (1984) 115-134.Chemical Abstracts Vol. 102 No. 173068f
R. Roque-Malherbe, V. Zelenenko, M.P. Glazunov and A.P. Gay,Method of determining the apparent diffusion activation energy of zeolites. Revista Cubana de Fisica Vol.4 (1984) 149-153 Chemical Abstracts Vol. 103 No. 184099p
R. Roque-Malherbe, M. Autie and A. Picart, Adsorption isotherm in microporous crystalline solids, Revista Cubana de Fisica Vol.4 (1984) 5-11. Chemical Abstracts Vol. 102 No. 32920r
R. Roque-Malherbe,C. de las Pozas, G. Rodriguez and G.M. Plavnik, Selectivity effect in catalysis by activation with Ni ions. Part II, Revista Cubana de Fisica Vol.4 (1984) 135-141, Chemical Abstracts Vol. 103 No. 221602v
C. Gonzales and R. Roque-Malherbe, General quantitative analytical method using X-ray diffraction, KINAM Vol.5 (1983) 67-74. Chemical Abstracts Vol. 99 No. 98206b.
R. Roque-Malherbe, C. Diaz and M. Autie, Moessbauer study of a natural mordenite, KINAM Vol. 5 (1983) 59-65., Chemical Abstracts Vol. 99 No. 56592f.
R. Roque-Malherbe, A. Dago and C. Diaz., Quantitative analysis of phases by powder X-ray diffraction using multilinear regression, Revista Cubana de Fisica Vol. 3 (1983) 105-115, Chemical Abstracts Vol. 101 No. 182704
R. Roque-Malherbe, Gas analysis by mass spectrometry, Revista Cubana de Fisica Vol. 3 (1983) 155-159 , Chemical Abstracts Vol. 101 No. 121986p
R. Roque-Malherbe, Polymolecular adsorption isotherm, Revista Cubana de Fisica Vol. 3 (1983) 161-165 Chemical Abstracts Vol. 101 No. 198646k


Luis Montero, Roland Roque, ArĂ­stides Rosado, JosĂ© FernĂĄndez Bertran: CNDO/SM calculations on dimeric and trimeric species of CO. Journal of Molecular Structure Theochem 11/1981; 85(s 3–4):393–395., DOI:10.1016/0166-1280(81)85040-3
R. Roque-Malherbe , B.S. Bokstein and A.A. Zhujovitskii, Effect of grain boundaries in the low temperature oxidation of metals, Revista CNIC Vol. 12 (1981) 95-98 , Chemical Abstracts Vol. 98 No. 20337s
R. Roque-Malherbe and F. Morales, Capacitive Thermal Analysis, Revista CNIC Vol 12 (1981) 393-395. Chemical Abstracts Vol. 97 No. 192227t
R. Roque-Malherbe, Statistical thermodynamic foundation of the entropy concept, Revista Cubana de Fisica Vol. 1 (1981) 141-157, Chemical Abstracts Vol. 98 No. 168013
R. Roque-Malherbe and R. Pascual, A new approach to some actual topics in electrochemistry. Part I. ,The Tafel equation and the dependence of the transfer coefficient., Revista CNIC Vol. 11 (1980) 17-21. Chemical Abstracts Vol. 95 No. 140775t
R. Pascual and R. Roque-Malherbe, A new approach to some actual topics in electrochemistry. Part II. The metal solution interface in equilibrium conditions. Revista CNIC Vol. 11 (1980) 23-27. Chemical Abstracts Vol. 95 No. 140776u
R. Pascual and R. Roque-Malherbe, A new approach to some actual topics in electrochemistry.Part III. The frequency dependence of the capacity at the metal solution interface. Revista CNIC Vol. 11 (1980) 29-31.Chemical Abstracts Vol. 95 No. 140777v
R. Roque-Malherbe, Mechanism of the oxidation of Fe-Ni alloys, Revista CNIC Vol. 11 (1980) 79-91,Chemical Abstracts Vol. 96 No. 39015r
R. Roque-Malherbe, B.S. Bokstein and A.A. Zhujovitskii, Study of the oxidation of Fe by NO. Revista de Metalurgia CENIM Vol. 15 (1979) 287-291.Chemical Abstracts Vol. 93 No. 13843x.
R. Roque-Malherbe, F. Ruiz and A. Perez-Reyes, Metallophysics of Fe-Ni and Fe-Ni-Cr surface alloys, Revista de Metalurgia CENIM Vol. 15 (1979) 373-378. Chemical Abstracts Vol. 93 No. 77057b
R. Roque-Malherbe, A.A. Zhujovitskii and B.S. Bokstein, Kinetics of Fe oxidation with NO.,Revista CNIC Vol 8. (1977) 41-50, Chemical Abstracts Vol. 93 No. 13799n
R. Roque-Malherbe, R. Sanchez and A. Rosado, Mass spectrometric study of the effect of CO on Ni, Revista CNIC Vol. 8 (1977) 87-88. Chemical Abstracts Vol. 90 No. 161499k
R. Roque-Malherbe, D. Coutin and A. Brito. Rocks, Carbon dioxide adsorption on a natural clinoptilolite, Revista CNIC Vol. 8 (1977) 83-91, Chemical Abstracts Vol. 93 No. 98592ni
R. Roque-Malherbe and J. Buttner, Qualitative study of the action of NO over Fe, Revista CNIC Vol. 6(1975)1-6, Chemical Abstracts Vol. 84 No. 93517w
R. Roque-Malherbe. Determination of the heterogeneity of surfaces, Revista CNIC Vol. 5(1974)315-322, Chemical Abstracts Vol. 82 No. 145539k
Patents
R. Roque-Malherbe: Silica mesoporous materials .. Ref. No: US WO(concealed information), IPC: C01B33/12; C01B33/00, Year: 05/2006
R. Roque-Malherbe: System and method for removing heavy metals from water. Ref. No: Patent application Publication Number: US2004/0055958 A1, Year: 03/2004
R. Roque-Malherbe: Procedure for the obtainment of a zeolite acid catalyst from a modified clinoptilolite or heulandite natural zeolite.. Ref. No: Patent Certificate No. 22083 ONIITEM, Cuba, Year: 01/1992
A. Jacas, M. Hernandez-Velez, R. Roque-Malherbe, ONIITEM: Biocompatible material obtained from a synthetic zeolite.. Ref. No: Patent solicitude RPI: 61 /91, ONIITEM, Cuba (1991)., Year: 03/1991
Rolando M. A. Roque-Malherbe, Vigil, H. Vlllavicencio, M. hernandez: Solid electrolytes prepared with modified zeolites.. Ref. No: Patent solicitude RPI: 72/90, ONIITEM, Cuba, Year: 01/1990
R. Roque-Malherbe, A. Montes: Coupling of thermo-dielectric and thermo-differential analysis.. Ref. No: Patent Certificate No. 21922, ONIITEM, Cuba, Year: 01/1990
Rolando M. A. Roque-Malherbe, M. hernandez-Velez, O. Raymond, A. Alvarado: Technical ceramics from natural zeolites. Ref. No: Patent solicitude RPI: 38/89 ONIITEM, Cuba, Year: 01/1989
Rolando M. A. Roque-Malherbe, C. de las Pozas: Synthesis of zeolite A using natural zeolites as raw materials.. Ref. No: Patent solicitude RPI: 160/89, ONIITEM, Cuba, Year: 01/1989
Rolando M. A. Roque-Malherbe, O. Raymond, A. Alvarado, M. hernandez-Velez: Abrasives from natural zeolites.. Ref. No: Patent solicitude RPI: 200/89 ONIITEM, Cuba, Year: 01/1989
Rolando M. A. Roque-Malherbe, Carlos de las Pozas: Synthesis of Zeolite X from natural zeolites. Ref. No: Patent solicitude: RPI: 83/87,, Year: 08/1987
Rolando M. A. Roque-Malherbe, A Montes, M Hernandez-Velez, A Rodriguez-Rivero: Equipment and method for the determination of the dielectric behavior of materials.. Ref. No: Patent Certificate No. 21746 ONIITEM, Cuba, Year: 03/1987
R. Roque-Malherbe: Method of Ni recovery by ionic exchange in natural clinoptilolite.. Ref. No: Patent Certificate No. 21503 ONIITEM, Cuba, Year: 01/1987
R. Roque-Malherbe: Use of furanic resins as gaseous NH3 sorbents. .. Ref. No: Patent certificate No. 21644 ONIITEM, Cuba, Year: 01/1986
Rolando Roque-Malherbe: Procedure for a Ni catalyst preparation. Year: 01/1983
R. Roque-Malherbe: Method of thermodielectric analysis.. Ref. No: Patent Certificate No. 21059 ONIITEM, Cuba, Year: 01/1982
R. Roque-Malherbe: Procedure for Ni extraction by ionic exchange in natural zeolites. Ref. No: Patent Certificate No. 21055 ONIITEM, Cuba, Year: 01/1982
Conference Proceedings
L. Fuentes-Cobas, S. Nieto, C. Neira, R. Polanco, R. Roque-Malherbe: In-situ XRD high temperature structural study of proton conduction in BaCe0.95Y0.05O3-d and BaCe0.95Yb0.05O3-d perovskites. 43rd World Chemistry Congress, San Juan, PR; 10/2011
F. Diaz-Castro J. A. Santana, R. Roque-Malherbe: DFT calculations on the interaction between a simulated silica surface and the carbon dioxide molecule. 43rd World Chemistry Congress, San Juan, PR, August 2011.; 10/2011
R. Roque-Malherbe, J. A. Santana, F. Diaz-Castro: A van der Waals DFT calculations of CO2 interaction with silica surface. 43rd World Chemistry Congress, San Juan, PR, Puerto Rico; 10/2011
F. Marquez-Linares, O. Uwakweh, N. Lopez, E. Chavez, R. Polanco, C. Morante, J. M. Sanz, E. Elizalde, C. Neira, S. Nieto, R. Roque-Malherbe: Study of the surface chemistry and morphology of single walled carbon nanotube (SWCNT)-magnetite composites, NanoTech 2010, Anaheim, CA, June 2010.. NanoTech 2010, Anaheim, CA; 06/2010
Rolando M. A. Roque-Malherbe, L Lemez, L Lopez-Colado, A. Montes: Physico Chemical parameters for the application of natural zeolites in water adsorption.. Zeolites

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